Commodity Production Costs Report

Benzene Production from Pygas (Extractive Distillation Process)

Benzene Operating Costs & Plant Construction Costs

250 kta United States-based plant | 107 Pages | Issue C | Q3 2024
Starting at $799 USD | See Report Editions Prices

This report examines the costs related to Benzene production from pyrolysis gasoline (pygas) in the United States using a typical extractive distillation process. Initially, pygas is fractionated into 3 hydrocarbon cuts. The C6s fraction is then fed to an extractive distillation system, using N-formylmorpholine (NFM) as solvent. to recover benzene.

The report provides a comprehensive study of Benzene production and related Benzene production cost, covering three key aspects: a complete description of the Benzene production process examined; an in-depth analysis of the related Benzene plant capital cost (Capex); and an evaluation of the respective Benzene plant operating costs (Opex).

The Benzene production process description includes a block flow diagram (BFD), an overview of the industrial site installations, detailing both the process unit and the necessary infrastructure, process consumption figures and comprehensive process flow diagrams (PFD). The Benzene plant capital cost analysis breaks down the Capex by plant cost (i.e., ISBL, OSBL and Contingency); owner's cost; working capital; and costs incurred during industrial plant commissioning and start-up. The Benzene plant operating costs analysis covers operating expenses, including variable costs like raw materials and utilities, and fixed costs such as maintenance, labor, and depreciation.

Key reference(s): ?

Benzene Production Cost Report Process Schematic

The process under analysis comprises two major sections: (1) Benzene Purification; and (2) Hydrogen Purification.

Benzene Purification. First, the pyrolysis gasoline, a hydrocarbons stream with carbon chains ranging from C5 to C12, is separated into three hydrocarbons cut. Both the light and heavy cuts are sold to nearby facilities. The intermediate cut, containing C6 hydrocarbons, is then fed with hydrogen to a pretreatment reactor. There, diolefinic material in the pyrolysis gasoline is hydrotreated in the presence of catalysts (cobalt molybdate on alumina). The diolefins in the pyrolysis gasoline feed are converted to olefins, which are then saturated. Also, thiophene and other sulfur compounds in the pyrolysis gasoline are converted to H2S. The regenerated aromatic stream is subjected to a extractive distillation. In the extractive distillation process, N-formylmorpholine (NFM) is mixed with the feed stream in order to alter the vapour pressure of the components to be separated. The solvent lowers the vapour pressure of benzene in the feed stream more than the other non-aromatic hydrocarbons. Given the shift in the vapour pressures, benzene is recovered alongside with the solvent fed to column. The rich-benzene solvent is fed to a stripping column to recover the solvent, through the column's bottom, and benzene, through the column's top.

Hydrogen Purification. Hydrogen stream is fed to the bottom of a multi-stage absorber column. The absorption is conducted in a counter-current flow. The purpose is to remove residual hydrocarbons from the hydrogen-rich feed stream, avoiding the build-up of impurities in the process. The washed hydrogen-rich gas is compressed and heated, before being directed to pretreatment reactor.

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  • Production Process Information
  • Process Consumptions
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  • Operating Cost Summary
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 80 Pages | 22 Tables | 9 Images

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  • Operating Cost Summary
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 90 Pages | 28 Tables | 13 Images

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Table of Contents


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  • Production Process Information
  • Process Consumptions
  • Labor Requirements
  • Plant Capital Cost Summary
  • Operating Cost Summary
  • Production Costs Datasheet
  • Plant Capital Cost Details
  • Operating Cost Details
  • Plant Cost Breakdowns
  • Plant Capacity Assessment
  • Process Flow Diagrams
  • Costs in Different Countries Add-on
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  • 107 Pages | 34 Tables | 22 Images
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Content Highlights

Plant Capital Cost Summary

Summary outlining the capital cost required for building the Benzene production plant examined.

Plant Capital Cost Details

Detailing of fixed capital (ISBL, OSBL & Owner’s Cost), working capital and additional capital requirements.

Plant Cost Breakdowns

Breakdown of Benzene process unit (ISBL) costs and infrastructure (OSBL) costs; plant cost breakdown per discipline.

Operating Costs Summary

Summary presenting the operating variable costs and the total operating cost of the Benzene production plant studied.

Operating Cost Details

Detailing of utilities costs, operating fixed costs and depreciation.

Plant Capacity Assessment

Comparative analysis of capital investment and operating costs for different Benzene plant capacities.

Production Process Information

Block Flow Diagram, descriptions of process unit (ISBL) and site infrastructure (OSBL).

Process Consumptions

Raw materials and utilities consumption figures, by-products credits, labor requirements

Process Diagrams

Process flow diagrams (PFD), equipment list and industrial site configuration

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