Epichlorohydrin from Propylene (Allyl Chloride Intermediate)
Epichlorohydrin Production Costs Report | Issue B | Q3 2024
Report Details |
80 kta United States-based plant | Q3 2024 | 107 pages |
This report presents a cost analysis of a 80 kta (kilo metric ton per annum) United States-based plant. You can add a customized cost analysis, assuming another location (country), when ordering a premium edition of this report.
Report Abstract
This feasibility study provides an economic analysis of Epichlorohydrin (ECH) production from propylene and chlorine in the United States. Initially, propylene is chlorinated, generating allyl chloride, which is reacted with hypochlorous acid, formed by chlorine dispersion in water. Finally, the glycerol dichlorohydrins generated are hydrolyzed with calcium hydroxide, yielding ECH.
The report provides a comprehensive study of Epichlorohydrin production and related Epichlorohydrin production cost, covering three key aspects: a complete description of the Epichlorohydrin production process examined; an in-depth analysis of the related Epichlorohydrin plant capital cost (Capex); and an evaluation of the respective Epichlorohydrin plant operating costs (Opex).
The Epichlorohydrin production process description includes a block flow diagram (BFD), an overview of the industrial site installations, detailing both the process unit and the necessary infrastructure, process consumption figures and comprehensive process flow diagrams (PFD). The Epichlorohydrin plant capital cost analysis breaks down the Capex by plant cost (i.e., ISBL, OSBL and Contingency); owner's cost; working capital; and costs incurred during industrial plant commissioning and start-up. The Epichlorohydrin plant operating costs analysis covers operating expenses, including variable costs like raw materials and utilities, and fixed costs such as maintenance, labor, and depreciation.
Process Schematic
The process under analysis comprises three major sections: (1) Allyl Chloride Reaction; (2) Propylene Recovery; and (3) Epichlorohydrin (ECH) Production.
Allyl Chloride Reaction. Initially, chemical grade propylene is preheated, mixed with chlorine and fed to a reactor where the chlorination reaction is carried out in the vapor phase, generating allyl chloride and some by-products. The chlorination products are cooled and then directed to the Prefractionator, where a stream rich in organic chlorides is separated from unreacted propylene and hydrogen chloride. The organic chlorides are routed to two distillation columns for the removal of light-end impurities and heavy-end impurities.
Propylene Recovery. The distillate from the Prefractionator is washed countercurrently with water in an absorber, in such a way that the hydrogen chloride is absorbed forming a hydrogen chloride solution, removed from column bottom. The gaseous stream from the overhead of the absorber upstream is fed to a Caustic Scrubber, where residual hydrogen chloride is removed. The washed propylene gas is compressed in a multi-stage compressor and then recycled to preheating.
Epichlorohydrin Production. The allyl chloride stream is reacted with hypochlorous acid, formed in turn by chlorine dispersion in water. The chlorohydrination reaction is conducted in the liquid phase, adiabatically. The liquid product from this reaction is passed through a separator where an aqueous phase, containing hypochlorous acid, is recycled, and a hydrocarbon phase, containing glycerol dichlorohydrins, is reacted with calcium hydroxide, yielding Epichlorohydrin product. The crude ECH stream is routed to one stripper and two distillation columns for the removal of calcium chloride, light-end impurities and heavy-end impurities.
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Production Process Information
Process Consumptions
Labor Requirements
Plant Capital Cost Summary
Operating Cost Summary
Production Costs Datasheet
Plant Capital Cost Details
Operating Cost Details
Plant Cost Breakdowns
Plant Capacity Assessment
Process Flow Diagrams
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Content Highlights
Plant Capital Cost Summary
Summary outlining the capital cost required for building the Epichlorohydrin production plant examined
Plant Capital Cost Details
Detailing of fixed capital (ISBL, OSBL & Owner’s Cost), working capital and additional capital requirements
Plant Cost Breakdowns
Breakdown of Epichlorohydrin process unit (ISBL) costs and infrastructure (OSBL) costs; plant cost breakdown per discipline
Operating Costs Summary
Summary presenting the operating variable costs and the total operating cost of the Epichlorohydrin production plant studied
Operating Cost Details
Detailing of utilities costs, operating fixed costs and depreciation
Plant Capacity Assessment
Comparative analysis of capital investment and operating costs for different Epichlorohydrin plant capacities
Production Process Information
Block Flow Diagram, descriptions of process unit (ISBL) and site infrastructure (OSBL)
Process Consumptions
Raw materials and utilities consumption figures, by-products credits, labor requirements
Process Diagrams
Process flow diagrams (PFD), equipment list and industrial site configuration
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This report presents a economic analysis of Epichlorohydrin production from allyl chloride and chlorine in the United States using a typical hypochlorination process. Initially, allyl chloride is reacted with hypochlorous acid, formed by chlorine dispersion in water. The glycerol dichlorohydrins generated are then treated with calcium hydroxide to promote epoxidation, yielding ECH.
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Epichlorohydrin from Propylene (Allyl Alcohol Intermediate)
This study presents a techno-economic analysis of Epichlorohydrin production from propylene and chlorine in the United States. In this process, propylene is subjected to an acetoxylation reaction, followed by hydrolysis, generating allyl alcohol, which is then chlorinated, yielding glycerol dichlorohydrins. Finally, the glycerol dichlorohydrins generated are reacted with calcium hydroxide, yielding Epichlorohydrin.
Details: 110 kta United States-based plant | Q3 2024 | 107 pages | Issue C From $1,199 USD
The cost analyses presented in this report target a 110 kta (kilo metric ton per annum per annum) United States-based plant. For those interested in cost analyses considering other plant capacities and/or locations, Intratec offers a customized analysis as an optional feature.
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